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Scheuermann, M. L.; Rheingold, A. L.; Williams, B. S.. 2009. Reversible Carbonylation of an [NCN]PtMe Pincer Complex and Direct Evidence of Alkyl Migration. Organometallics 28: 1613-1615. Full Article

[NCN]PtMe (1) reacts with CO initially to form an adduct (2) and then again to form a carbonyl acyl complex (3). Reaction of 3 with Me3NO generates 2 by alkyl migration rather than carbonyl deinsertion.

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